期刊论文

Kuang, DZ

中文

无机化学学报

1001-4861

2022

38

1

103-110

10.11862/CJIC.2022.026

功能金属有机化合物湖南省重点实验室资助；

本校为第一且通讯机构

在乙醇溶液中以3⁃乙氧基水杨醛和间苯二甲酰肼反应,制备双(3⁃乙氧基水杨醛)缩间苯二甲酰腙(H_(4)L)配体。用H_(4)L分别与二丁基氧化锡和三苯基氢氧化锡甲醇溶剂热反应,合成了双(3⁃乙氧基水杨醛)缩间苯二甲酰腙四丁(苯)基二锡配合物:Bu_(4)Sn_(2)L(T1)和Ph_(4)Sn_(2)L(T2)。用元素分析、红外光谱、紫外可见光谱、核磁共振谱以及单晶X射线衍射表征了H_(4)L和配合物的结构。H_(4)L的分子式为C_(26)H_(26)N_(4)O_(6),晶体属单斜晶系C2/c空间群,2个甲酰肼缩(3⁃乙氧基)水杨醛呈顺式对称构型。T1的分子式为C_(42)H_(58)N_(4)O_(6)Sn_(2),晶体属正交晶系Pbcn空间群,H_(4)L的2个甲酰肼缩(3⁃乙氧基)水...

The bis(3-ethoxysalicylaldehyde) 1,3-benzyldiacyl hydrazone (H4L) ligand was prepared by the reaction of 3-ethoxysalicylaldehyde with benzene-1,3-dicarbohydrazide in ethanol solution. Bis(3-ethoxysalicylaldehyde) 1,3-benzyldiacyl hydrazone tetrabutyl(phenyl)ditin, Bu4Sn2L (T1) and Ph4Sn2L (T2), were synthesized by solvothermal reaction of H4L with dibutyltin oxide and triphenyltin hydroxide in methanol, respectively. The structures of ligand and complexes were characterized by elemental analysis, IR, UV-Vis spectroscopy, NMR, and single-crystal...