期刊论文

Zhang, Chun-Hua

英文

Inorganic Chemistry Communications

1387-7003

2011

14

2

444-446

10.1016/j.inoche.2010.12.028

This work was financially supported by the Construct Program of the Key Discipline in Hunan Province , Distinguished Young Cadreman of Hunan Province (2008), Science Foundation of Hengyang Normal University of China ( 10B67 ) and the Scientific Research Fund of Hunan Provincial Education Department ( 10C0473 ).

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A new three-dimensional porous Zinc(II) metal-organic framework [NH 2Et2][Zn(BTC)]•H2O (1) was synthesized by the self-assembly of 1,3,5-benzenetricarboxy acid (H3BTC) and Zn(II) salt in diethylformamide (DEF), and characterized by single-crystal X-ray structure determination, thermogravimetric analysis and X-ray powder diffraction studies. The adsorption behavior shows that compound 1 has selective adsorption capacities of CO2 over N2 after the removal of the water molecules w...