期刊论文

Jiang Wujiu

中文

有机化学

0253-2786

2014

34

11

2288-2295

10.6023/cjoc201404037

(13JJ3112):the Hunan Provincial Natural Science Foundation of China (,2013TZ2025,2014NK3086,2014FJ3060):the Scientific&Technological Projects of Hunan Province of China (,13K105,14K104):the Open Fund Project of Key Laboratory in Hunan Universities (,13K03,13K04,13K05):the Founda-tion of Key Laboratory of Functional Organometallic Materials, University of Hunan Province (14C0171):the Scientific Research Fund of Hunan Provincial Education Department of China (Nos,12C45,13A21):the Science Foundation of Hengyang Normal University of China (13JJ3112):湖南省自然科学基金 (,2013TZ2025,2014NK3086,2014FJ3060):湖南省科技计划 (,13K105,14K104):湖南省普通高等学校重点实验室开放基金 (,13K03,13K04,13K05):功能金属有机材料湖南省普通高校重点实验室开放基金 (14C0171):湖南省教育厅基金项目 (,12C45,13A21):衡阳师范学院科学基金

本校为第一且通讯机构

通过微波辅助方法合成了系列的边臂修饰的水杨醛缩邻氨基酚Schiff 碱及其正丁基锡(IV)配合物, 并通过~1H NMR, ~(13)C NMR, IR, UV-vis, 元素分析和X 射线单晶衍射表征了化合物的结构; 测试了配体及配合物的荧光性能, 探讨了配合物的荧光发光机理.

A series of the salicylaldehyde-o-aminophenol Schiff base with appended donor functionality and their n-butyltin(IV) complexes have been synthesized and characterized by 1H NMR and 13C NMR, IR, UV-vis, elemental analysis and single-crystal X-ray study. The fluorescence spectra of ligands and complexes have been tested, and the fluorescent light-emitting mechanism has been preliminary stud...