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Poly[diaqua[μ4-4-(isonicotinamido)phthalato]nickel(II)] displaying an sra topology

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成果类型:
期刊论文
作者:
Chen, Man-Sheng*;Xu, Jin-Sheng;Deng, Yi-Fang;Zhang, Chun-Hua
通讯作者:
Chen, Man-Sheng
作者机构:
[Deng, Yi-Fang; Chen, Man-Sheng; Xu, Jin-Sheng; Zhang, Chun-Hua] Hengyang Normal Univ, Key Lab Funct Organometall Mat, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
通讯机构:
[Chen, Man-Sheng] H
Hengyang Normal Univ, Key Lab Funct Organometall Mat, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
语种:
英文
关键词:
4-(isonicotinamido)phthalate ligand;coordination polymers;crystal structure;metal-organic frameworks;nickel complex;sra topology
期刊:
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
ISSN:
2053-2296
年:
2013
卷:
69
期:
10
页码:
1124-1127
基金类别:
Open Fund Project of Key Laboratories in Hunan Universities [11 K009]; Key Project of Science and Technology Plan of Hunan Province [2012 F J2002]; Natural Science Foundation of Hunan Province of ChinaNatural Science Foundation of Hunan Province [13 J J6069]
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
In the title compound, [Ni(C14H8N2O 5)(H2O)2]n, the NiII cation is six-coordinate with a slightly distorted octahedral coordination geometry and the 4-(isonicotinamido)phthalate ligand links the NiII centres into a three-dimensional structure with sra topology. The structure is also stabilized by N - H&mellip;O hydrogen bonding between the uncoordinated amide groups of the ligand and extensive O - H&mellip;O hydrogen bonding between the two coordinated water molecules. The magnetic and thermal stability properties of the title compound are also discussed. ©2013 International Union of Crys...

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