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Porous zinc(II) frameworks with 5-(isonicotinamido)isophthalate: Syntheses, structures and properties

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成果类型:
期刊论文
作者:
Chen, Man-Sheng;Chen, Min;Okamura, Taka-aki;Sun, Wei-Yin*;Ueyama, Norikazu
通讯作者:
Sun, Wei-Yin
作者机构:
[Sun, Wei-Yin; Chen, Min; Chen, Man-Sheng] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China.
[Chen, Man-Sheng] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
[Ueyama, Norikazu; Okamura, Taka-aki] Osaka Univ, Dept Macromol Sci, Grad Sch Sci, Osaka 5600043, Japan.
通讯机构:
[Sun, Wei-Yin] N
Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China.
语种:
英文
关键词:
Coordination polymer;Zinc(II) complex;Crystal structure;Sorption property
期刊:
Microporous and Mesoporous Materials
ISSN:
1387-1811
年:
2011
卷:
139
期:
1-3
页码:
25-30
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [20731004, 20721002]; National Basic Research Program of ChinaNational Basic Research Program of China [2007CB925103, 2010CB923303]; Grants-in-Aid for Scientific ResearchMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [20550063] Funding Source: KAKEN
机构署名:
本校为其他机构
院系归属:
化学与材料科学学院
摘要:
Two new three-dimensional (3D) coordination polymers [Zn(INAIP)] ·2DMF (1) and [Zn(INAIP)]·9H2O (2) have been synthesized by reactions of Zn(NO3)2·6H 2O with 5-(isonicotinamido)isophthalic acid (H2INAIP) in N,N-dimethylformamide (DMF) and N,N-diethylformamide (DEF), respectively. The change of solvent leads to the formation of neutral frameworks with different structure, topology as well as different pore size and shape. The X-ray crystallographic structural analysis revealed that complex 1 is an unusual 3D architecture with (3, 6)-connected rutile (rtl) topology containin...

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