Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(II) frameworks

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成果类型：

期刊论文

作者：

Chen, Man-Sheng;Chen, Min;Takamizawa, Satoshi;Okamura, Taka-aki;Fan, Jian;...

通讯作者：

Sun, Wei-Yin

作者机构：

[Fan, Jian; Sun, Wei-Yin; Chen, Min; Chen, Man-Sheng] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China.

[Chen, Man-Sheng] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.

[Takamizawa, Satoshi] Yokohama City Univ, Grad Sch Nanobiosci, Kanazawa Ku, Kanagawa 2360027, Japan.

[Okamura, Taka-aki] Osaka Univ, Dept Macromol Sci, Grad Sch Sci, Osaka 5600043, Japan.

通讯机构：

[Sun, Wei-Yin] N

Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China.

语种：

英文

期刊：

Chemical Communications

ISSN：

1359-7345

年：

2011

卷：

期：

页码：

3787-3789

DOI：

10.1039/c0cc04689b

基金类别：

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [20731004, 21021062]; National Basic Research Program of ChinaNational Basic Research Program of China [2007CB925103, 2010CB923303]; Grants-in-Aid for Scientific ResearchMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [23655049] Funding Source: KAKEN

机构署名：

本校为其他机构

院系归属：

化学与材料科学学院

摘要：

A unique 4-fold interpenetrated (10,3)-b copper(ii) framework exhibits reversible dehydration and rehydration in a single-crystal-to-single-crystal (SC-SC) process, and the dehydrated material can encapsulate CH3OH molecules, again in a SC-SC fashion, and shows selective adsorption of H 2 and CO2 ove...

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Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(II) frameworks

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