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Tuning iron-amine electronic coupling by different aromatic bridges based on ferrocene-ethynyl-triarylamine systems

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成果类型:
期刊论文
作者:
Jiang, Penghui;Yang, Xiaofei;Cao, Na;Zhu, Xiaoming;Zhang, Fuxing;...
通讯作者:
Sheng Hua Liu<&wdkj&>Ya-Ping Ou
作者机构:
[Cao, Na; Ou, Ya-Ping; Jiang, Penghui; Zhu, Xiaoming; Zhang, Fuxing] Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
[Cao, Na; Ou, Ya-Ping; Jiang, Penghui; Zhu, Xiaoming; Zhang, Fuxing] Hengyang Normal Univ, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.
[Cao, Na; Ou, Ya-Ping; Jiang, Penghui; Zhu, Xiaoming; Zhang, Fuxing] Hengyang Normal Univ, Key Lab Funct Organomet Mat, Hunan Prov Coll, Hengyang 421008, Hunan, Peoples R China.
[Cao, Na; Ou, Ya-Ping; Jiang, Penghui; Zhu, Xiaoming; Zhang, Fuxing] Hunan Engn Res Ctr Monitoring & Treatment Heavy M, Hengyang 421001, Hunan, Peoples R China.
[Liu, Sheng Hua; Yang, Xiaofei] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China.
通讯机构:
[Sheng Hua Liu] K
[Ya-Ping Ou] C
Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, PR China<&wdkj&>College of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, PR China<&wdkj&>Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Hengyang Normal University, Hengyang 421008, PR China<&wdkj&>Key Laboratory of Functional Organometallic Materials of Hunan Province College, Hengyang Normal University, Hengyang, Hunan 421008, PR China<&wdkj&>Hunan Engineering Research Center for Monitoring and Treatment of Heavy Metals Pollution in the upper Reaches of Xiangjiang River, Hengyang, Hunan 421001, PR China
语种:
英文
关键词:
Asymmetric mixed-valence systems;Electronic coupling;Ethynylferrocene;Spectroelectrochemistry;Triarylamine
期刊:
Inorganica Chimica Acta
ISSN:
0020-1693
年:
2022
卷:
532
页码:
120743
基金类别:
The authors acknowledge the financial support from National Natural Science Foundation of China (21602049), the Natural Science Foundation of Hunan Province, China (Nos. 2021JJ30058, 2017JJ3004), the Opening Subjects of Hunan Province Key Laboratory of Functional Metal-Organic Compounds (No. MO19K04), the Aid Programs for Technology Innovative Team, Key Discipline in Education Department of Hunan Province and Functional Metal-Organic Compounds of Hunan Science and Technology Innovation Team, and the Support Plan for Talents in Hengyang Normal University.
机构署名:
本校为第一机构
院系归属:
化学与材料科学学院
摘要:
The syntheses of a series of ferrocene (Fc)–ethynyl–triarylamine (TAA) inorganic–organic mixed-valence systems with different aromatic bridge linkers (Aryl = 1,4-phenyl [1], 1,4-naphthyl [2], 9,10-anthryl [3]) are reported in this study. These systems were accessible with good yields through the classical Sonogashira cross-coupling reactions of brominated intermediates, 1a, 2a, and 3a, with ethynylferrocene, respectively. Target compounds 1–3 were fully characterized by nuclear magnetic resonance, elemental analysis, and single-crystal X-ra...

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