Porous Organic Cage-Based Quasi-Solid-State Electrolyte with Cavity-Induced Anion-Trapping Effect for Long-Life Lithium Metal Batteries

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作者信息关键词期刊信息基础信息归属信息摘要

成果类型：

期刊论文

作者：

Wei-Min Qin;Zhongliang Li;Wen-Xia Su;Jia-Min Hu;Hanqin Zou;...

通讯作者：

Cai, Yue-Peng;Li, Kang;Zheng, Qifeng

作者机构：

[Jia-Min Hu; Wen-Xia Su; Wei-Min Qin; Zhixuan Wu; Hanqin Zou; Zhiqin Ruan] School of Chemistry, South China Normal University, Guangzhou, 510006, People's Republic of China

[Zhongliang Li] Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, 421008, People's Republic of China

[Yue-Peng Cai] School of Chemistry, South China Normal University, Guangzhou, 510006, People's Republic of China. caiyp@scnu.edu.cn

[Yue-Peng Cai] Guangzhou Key Laboratory of Energy Conversion and Energy Storage Materials, Guangzhou, 510006, People's Republic of China. caiyp@scnu.edu.cn

[Kang Li] School of Chemistry, South China Normal University, Guangzhou, 510006, People's Republic of China. likang5@m.scnu.edu.cn

通讯机构：

[Cai, Yue-Peng; Zheng, Qifeng; Li, Kang] S

School of Chemistry, South China Normal University, Guangzhou, 510006, People's Republic of China.

Guangzhou Key Laboratory of Energy Conversion and Energy Storage Materials, Guangzhou, 510006, People's Republic of China.

School of Chemistry, South China Normal University, Guangzhou, 510006, People's Republic of China. qifeng.

Guangzhou Key Laboratory of Energy Conversion and Energy Storage Materials, Guangzhou, 510006, People's Republic of China. qifeng.

语种：

英文

关键词：

Cavity-induced anion-trapping;Homogeneous Li+ flux;Lithium metal battery;Porous organic cage;Quasi-solid-state electrolyte

关键词(中文)：

光学期刊,光学期刊联盟,光学论文,光电资讯,光电社区,光学人物,光学专家,光学实验室,光学文献,编辑出版,光学权威,光学前沿,光学会议,微信智能应答服务,光学资源库,DOI代理注册,高功率激光,High Power Laser Science and Engineer,光子学研究,Photonics Research,中国光学快报,COL,Chinese Optics Letters,光学学报,中国激光,激光与光电子学进展

期刊：

纳微快报：英文版

ISSN：

2311-6706

年：

2025

卷：

期：

页码：

384-394

DOI：

10.1007/s40820-024-01499-x

基金类别：

supported by the National Natural Science Foundation of China (No. 92372123)； Guangdong Basic and Applied Basic Research Foundation (No. 2022A1515012057, 2022B1515020005, 2023B1515130004)；

机构署名：

本校为其他机构

院系归属：

化学与材料科学学院

摘要：

Porous organic cages (POCs) with permanent porosity and excellent host-guest property hold great potentials in regulating ion transport behavior, yet their feasibility as solid-state electrolytes has never been testified in a practical battery. Herein, we design and fabricate a quasi-solid-state electrolyte (QSSE) based on a POC to enable the stable operation of Li-metal batteries (LMBs). Benefiting from the ordered channels and cavity-induced anion-trapping effect of POC, the resulting POC-based QSSE exhibits a high Li(+) transference number o...

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Porous Organic Cage-Based Quasi-Solid-State Electrolyte with Cavity-Induced Anion-Trapping Effect for Long-Life Lithium Metal Batteries

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