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Porous Organic Cage-Based Quasi-Solid-State Electrolyte with Cavity-Induced Anion-Trapping Effect for Long-Life Lithium Metal Batteries.

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成果类型:
期刊论文
作者:
Wei-Min Qin;Zhongliang Li;Wen-Xia Su;Jia-Min Hu;Hanqin Zou;...
通讯作者:
Cai, Yue-Peng;Li, Kang;Zheng, Qifeng
作者机构:
[Jia-Min Hu; Wen-Xia Su; Wei-Min Qin; Zhixuan Wu; Hanqin Zou; Zhiqin Ruan] School of Chemistry, South China Normal University, Guangzhou, 510006, People's Republic of China
[Zhongliang Li] Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, 421008, People's Republic of China
[Yue-Peng Cai] School of Chemistry, South China Normal University, Guangzhou, 510006, People's Republic of China. caiyp@scnu.edu.cn
[Yue-Peng Cai] Guangzhou Key Laboratory of Energy Conversion and Energy Storage Materials, Guangzhou, 510006, People's Republic of China. caiyp@scnu.edu.cn
[Kang Li] School of Chemistry, South China Normal University, Guangzhou, 510006, People's Republic of China. likang5@m.scnu.edu.cn
通讯机构:
[Cai, Yue-Peng; Zheng, Qifeng; Li, Kang] S
School of Chemistry, South China Normal University, Guangzhou, 510006, People's Republic of China.
Guangzhou Key Laboratory of Energy Conversion and Energy Storage Materials, Guangzhou, 510006, People's Republic of China.
School of Chemistry, South China Normal University, Guangzhou, 510006, People's Republic of China. qifeng.
Guangzhou Key Laboratory of Energy Conversion and Energy Storage Materials, Guangzhou, 510006, People's Republic of China. qifeng.
语种:
英文
关键词:
Cavity-induced anion-trapping;Homogeneous Li+ flux;Lithium metal battery;Porous organic cage;Quasi-solid-state electrolyte
期刊:
纳微快报:英文版
ISSN:
2311-6706
年:
2025
卷:
17
期:
1
页码:
1-11
机构署名:
本校为其他机构
院系归属:
化学与材料科学学院
摘要:
Porous organic cages (POCs) with permanent porosity and excellent host-guest property hold great potentials in regulating ion transport behavior, yet their feasibility as solid-state electrolytes has never been testified in a practical battery. Herein, we design and fabricate a quasi-solid-state electrolyte (QSSE) based on a POC to enable the stable operation of Li-metal batteries (LMBs). Benefiting from the ordered channels and cavity-induced anion-trapping effect of POC, the resulting POC-based QSSE exhibits a high Li(+) transference number o...

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