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A new electrochemical method for the determination of trace molybdenum(VI) using carbon paste electrode modified with sodium dodecyl sulfate

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成果类型:
期刊论文
作者:
Deng, Pei-hong*;Feng, Yong-lan;Fei, Jun-jie
通讯作者:
Deng, Pei-hong
作者机构:
[Feng, Yong-lan; Deng, Pei-hong] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
[Fei, Jun-jie] Xiangtan Univ, Coll Chem, Xiangtan 411105, Hunan, Peoples R China.
通讯机构:
[Deng, Pei-hong] H
Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Hunan, Peoples R China.
语种:
英文
关键词:
Molybdenum;Morin;Sodium dodecyl sulfate;Carbon paste electrodes;Adsorptive anodic stripping voltammetry
期刊:
Journal of Electroanalytical Chemistry
ISSN:
1572-6657
年:
2011
卷:
661
期:
2
页码:
367-373
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21105024]; Science and Technology Department of Hunan Province [2011FJ3165]; Science and Technology Bureau of Hengyang City [2010KJ21]; Research Award Fund for Outstanding Young Teachers of Hunan Province [2011]; Education Department of Hunan Province [11CY002, 09K099]
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
A sensitive procedure was developed for the determination of trace molybdenum(VI) by adsorptive anodic stripping voltammetry based on the oxidation of molybdenum(VI)-2′,3,4′,5,7-pentahydroxyflavone (morin) complex at a sodium dodecyl sulfate modified carbon paste electrode (denoted as SDS/CPE). Compared with the poor response at a conventional paste electrode, the electrooxidation of molybdenum(VI)-morin complex at the SDS/CPE was greatly improved, as confirmed from the significant enhancement of peak current and the negative shift of peak potentials. The optimum conditions for the...

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