Crystal Structure, and Magnetic and Fluorescence Properties of a New Terbium(III) Complex, [Tb(L)(3)(2,2 \'-bipy)(DMF)]center dot(2,2 \'-bipy) - 成果

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Crystal Structure, and Magnetic and Fluorescence Properties of a New Terbium(III) Complex, [Tb(L)(3)(2,2 '-bipy)(DMF)]center dot(2,2 '-bipy)

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作者信息关键词期刊信息基础信息归属信息摘要

成果类型：

期刊论文

作者：

Yang, Ying-Qun*;Zhang, Shao-Hua;Tan, Hong-Bo;Fu, Li-Xia

通讯作者：

Yang, Ying-Qun

作者机构：

[Zhang, Shao-Hua; Yang, Ying-Qun] Hengyang Normal Univ, Key Lab Funct Organometall Mat, Hunan Prov Coll, Dept Chem & Mat Sci, Hengyang City 421008, Hunan, Peoples R China.

[Tan, Hong-Bo; Fu, Li-Xia; Yang, Ying-Qun] Hengyang Xicheng Organ Chem Plant, Hengyang City 421008, Hunan, Peoples R China.

通讯机构：

[Yang, Ying-Qun] H

Hengyang Normal Univ, Key Lab Funct Organometall Mat, Hunan Prov Coll, Dept Chem & Mat Sci, Hengyang City 421008, Hunan, Peoples R China.

语种：

英文

关键词：

Terbium(III) Complex;Crystal Structure;Magnetic and Fluorescence Properties

期刊：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES

ISSN：

0932-0776

年：

2013

卷：

期：

页码：

1269-1272

DOI：

10.5560/ZNB.2013-3034

基金类别：

Fund of Science and Technology Committee of Hunan Province [2012GK3030]; Scientific Research Fund of Hunan Provincial Education DepartmentHunan Provincial Education Department [11C0186]; Hengyang Bureau of Science and Technology [2011kG28]; Key Discipline Project of Hunan Province

机构署名：

本校为第一且通讯机构

院系归属：

化学与材料科学学院

摘要：

A new Tb(III) complex, [Tb(L)3(2,2´-bipy)(DMF)]·(2,2´- bipy) (1), has been synthesized with 2-benzoylbenzoic acid (HL) and 2,2´-bipyridine (2,2´-bipy) as ligands. In 1, the Tb(III) ion is coordinated by nine atoms to give a distorted tri-capped trigonal-prismatic geometry. The magnetic and fluorescence properties of 1 are discussed. Compound 1 is paramagnetic in the temperature range of 300 - 24 K, and when the temperature decreases from 22 to 2 K, it exhibits weak ferromagnetism. The compound shows four intense fluorescence emission bands...

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Crystal Structure, and Magnetic and Fluorescence Properties of a New Terbium(III) Complex, [Tb(L)(3)(2,2 '-bipy)(DMF)]center dot(2,2 '-bipy)

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