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Crystal structure, magnetic, fluorescent, electrochemical properties and thermal stability of a new copper(II) coordination polymer [Cu-2(C5H4NCOO)(2)(C7H5N4)(2)](n)

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成果类型:
期刊论文
作者:
Li, Wei;Li, Chang-Hong;Yang, Ying-Qun;Li, Heng-Feng*
通讯作者:
Li, Heng-Feng
作者机构:
[Li, Wei; Li, Heng-Feng] Cent S Univ, Sch Mat Sci & Engn, Changsha 410083, Hunan, Peoples R China.
[Li, Wei; Yang, Ying-Qun] Hengyang Normal Univ, Dept Chem & Mat Sci, Hunan Prov Coll, Key Lab Funct Organomet Mat, Hengyang 421008, Hunan, Peoples R China.
[Li, Chang-Hong] Hunan Inst Technol, Coll Mat & Chem Engn, Hengyang 421002, Hunan, Peoples R China.
通讯机构:
[Li, Heng-Feng] C
Cent S Univ, Sch Mat Sci & Engn, Changsha 410083, Hunan, Peoples R China.
语种:
英文
关键词:
And electrochemical properties;Copper(II) coordination polymer;Crystal structure;Fluorescent;Magnetic;Thermal stability
期刊:
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
ISSN:
0932-0776
年:
2015
卷:
70
期:
4
页码:
215-219
基金类别:
Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [11JJ9006]; Key Project of Science and Technology Plan of Hunan Province [2012FJ2002]; Construct Program of the Key Discipline in Hunan Province
机构署名:
本校为其他机构
院系归属:
化学与材料科学学院
摘要:
A new copper(II) coordination polymer [Cu-2(C5H4NCOO)(2)(C7H5N4)(2)](n) (1) has been synthesized with 4-pyridinecarboxylate and 3-(pyridin-2-yl)-1,2,4-triazolyl ligands. The crystal structure shows that two neighboring copper(II) ions are coordinated with two deprotonated (anionic) 3-(pyridin-2-yl)-1,2,4-triazole ligands to form a binuclear structure. Adjacent binuclear units are linked by 4-pyridinecarboxylate anions to form a three-dimensional network structure. The magnetic, fluorescent, and electrochemical properties and thermal stability of 1 were studied. The results show that 1 exhibits...

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