Education Department of Hunan Province [2022JJ40009, 2024JJ6100]; Natural Science Foundation of Hunan Province [2023QD20]; Hengyang Normal University Foundation Program [23B0676]; Hunan Provincial Department of Education Outstanding Youth Project [202330046099]; Hengyang City Science and Technology Innovation Plan Project
机构署名：
本校为第一且通讯机构
院系归属：
化学与材料科学学院
摘要：
In this work, dual active-site Ti-incorporated metal-organic frameworks (MIL-125 and NH2-MIL-125) were synthesized by a simple solvothermal process and applied to prepare cyclohexanone oxime from cyclohexylamine oxidation. A low-temperature thermal calcination strategy was used for the modulation of surface properties while maintaining the crystal structure and morphology. The results demonstrated that novel bifunctional NH2-MIL-125@250 degrees C obtained from thermal calcination possessed a large surface area with both oxygen vacancies and surface hydroxyl-active sites, promoting the adsorpti...
