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(3,4)-Connected Twofold Interpenetrated Network with Right- and Left-Handed Helical Chains: Synthesis, Crystal Structure, and Luminescence Sensing

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成果类型:
期刊论文
作者:
Liu, Yang*;Feng, Yong-Lan;Fu, Wei-Wei;Li, Wei;Yang, Ying-Qun
通讯作者:
Liu, Yang
作者机构:
[Fu, Wei-Wei; Feng, Yong-Lan; Li, Wei; Yang, Ying-Qun; Liu, Yang] Hengyang Normal Univ, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang City, Hunan, Peoples R China.
通讯机构:
[Liu, Yang] H
Hengyang Normal Univ, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat, Hengyang City, Hunan, Peoples R China.
语种:
英文
关键词:
Interpenetrated network;Helix;Fluorescence sensing;Crystal structure;Zinc
期刊:
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN:
0044-2313
年:
2017
卷:
643
期:
15
页码:
968-972
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21461004]; Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [2016JJ5004]
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
The zinc(II) coordination polymer Zn2(L)2(bix)2·2H2O (1) [H2L = 4,4′‐methylenebis(oxy)dibenzoic acid, bix = 1,4‐bis(imidazole‐1‐yl‐methylene)‐benzene] was synthesized by hydrothermal reaction. The title compound was characterized by single‐crystal X‐ray diffraction analysis, IR spectroscopy, and elemental analysis. The crystal structure determination reveals that compound 1 displays a twofold interpenetrated 3D framework, in which the Zn atoms are connected by the H2L ligands into interesting right and left‐handed helical chains. Top...

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