期刊论文

Xu, Jin-Sheng

英文

Transition Metal Chemistry

0340-4285

2014

39

8

901-907

10.1007/s11243-014-9874-1

National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21461004]; Key Project of Science and Technology Plan of Hunan Province [2012FJ2002]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2014M552534XB]; Scientific Research Fund of Hunan Provincial Education DepartmentHunan Provincial Education Department [14A021]; Foundation of Key Laboratory of Functional Organometallic Materials; University of Hunan Province [13K06]; Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province; Hunan Provincial Key Discipline Construction

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Two Co(II) complexes, [Co(INAIP)(dib)]·4H2O and [Co(INAIP)(phen)(H2O)]·H2O have been synthesized by the reaction of 5-(isonicotinamido)isophthalic acid (H2INAIP) and CoSO4·7H2O, as well as N-donor ligands, namely 1,4-di(1-imidazolyl)benzene (dib) and 1,10-phenanthroline (phen) under hydrothermal conditions. Single-crystal X-ray diffraction analysis indicates that [Co(INAIP)(dib)]·4H2O has a two-dimensional (2D) double-layer network structure with a (4, 4) topology, while [Co(INAIP)(phen)(H2O)]·H2O displays a one-dimensional chain structure...