期刊论文

Dai-Zhi, Kuang

英文

Chinese Journal of Structural Chemistry

0254-5861

2006

25

8

919-922

This work was supported by the Natural Science Foundation of Hunan Province （No, 05JJ30016） and Science Foundation of Hengyang Normal Univelsity of China （2005A01）, the Basic Research of the Hunan Province （03JZY3036）

本校为第一且通讯机构

The title complex [Zn（L）（phen）（CH3OH）] （L = C8H6BrO4NS, aminomethanesulfonic acid 5-bromo-salicylaldelyde schiff base; phen = 1,10-phenanthroline） has been synthesized and characterized by X-ray diffraction method. The crystal belongs to monoclinic, space group P21/c with a = 1.8712（3）, b = 1.38008（19）, c = 0.83685（12） nm, β = 97.791 （2）°, Mr = 569.72, V = 2.1411 （5） nm^3, Z= 4, Dc = 1.767 g/cm^3,μ = 3.151 mm^-1, F（000） = 1144, the final R = 0.0402 and wR = 0.0885. The central Zn（Ⅱ） is six-coordinated by one nitrogen a...