期刊论文

Guo Dong-Cai

英文

Chinese Journal of Structural Chemistry

0254-5861

2006

25

6

752-756

Project supported by the Natural Science Foundation of Hunan Province （No. 05JJ30016）, Foundation of Education Committee of Hunan Province （05C001）, Foundation of Hengyang Sci. & Tech. Bureau （2005Cg10-23） and Fund for Distinguished Young Scholars of Hengyang Normal University （No. 2003C16）；

本校为第一且通讯机构

A one-dimensional chain cobalt(II) coordination polymer with 2,4,6-trimethyl-benzoic acid, 1,10-phenanthroline and cobalt perchlorate anhydrous has been synthesized in the solvent mixture of water/methanol and characterized. Crystal data for this complex: tetragonal, space group I4(I), a = 2.0356(2), c = 1.3779(3) nm, V = 5.7096(15) nm(3), M-r = 581.51, mu(MoK alpha) = 0.644, D-c = 1.353 g/cm(3), Z = 8, F(000) = 2424, final S = 1.005, R = 0.0404 and wR = 0.0865. The crystal structure shows that the cobalt ion is coordinated with two nitrogen atoms of one 1,10-phenanthroline molecule, three oxy...