期刊论文

Yang Ying-Qun

英文

Chinese Journal of Structural Chemistry

0254-5861

2007

26

9

1076-1080

Supported by the Construct Program of the Key Discipline in Hunan Province and the Foundation of Education Committee of Hunan Province （06C195）；

本校为第一且通讯机构

A one-dimensional chain-like coordination polymer [Mn(phen)(2,4,6-TMBA)(2)(H2O)](n) has been synthesized from 2,4,6-tlimethylbenzoic acid, 1,10-phenanthroline and anhydrous manganese(II) sulfate and then characterized. Crystal data for this complex: tetragonal, space group 141, a = 2.05643(16), b = 2.05643(16), c = 1.3939(2) nm, V = 5.8946(11) nm, M-r = 579.54, Z = 8, D-c = 1.306 g/cm(3), mu(MoK alpha) = 0.490 mm(-1), F(000) = 2424, S = 0.985, the final R = 0.0411 and wR = 0.0950. The Flack factor is -0.01(2). The crystal structure shows that two neighboring manganese(II) ions are linked toget...