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Synthesis, Crystal Structure and Electrochemical Properties of One-dimensional Chain Coordination Polymer [Co(II)(C_6H_5CH=CHCOOH)_2(4,4′-bipy)(H_2O)_5]_n

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成果类型:
期刊论文
作者:
Wei, Li*;Chang-Hong, Li;Xue, Nie;Ying-Qun, Yang;Yun-Fei, Kuang
通讯作者:
Wei, Li
作者机构:
[Ying-Qun, Yang; Yun-Fei, Kuang; Xue, Nie; Wei, Li] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
[Chang-Hong, Li] Hunan Inst Technol, Dept Chem Engn, Hengyang 421002, Peoples R China.
通讯机构:
[Wei, Li] H
Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
语种:
英文
关键词:
cobalt(II) coordination polymer;crystal structure;electrochemical property analysis
关键词(中文):
钴(Ⅱ);聚合物;晶体结构;电气化学
期刊:
Chinese Journal of Structural Chemistry
ISSN:
0254-5861
年:
2007
卷:
26
期:
12
页码:
1486-1490
基金类别:
Supported by the Foundation of Education Committee of Hunan Province (06C195), the Research Award Fund for Outstanding Young Teachers of Hengyang Normal University (2006), and the coastruct program of the Key Discipline in the Eleventh Five Year Plan of Higher Learning of Education in Hunan Province
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
A one-dimensional chain coordination polymer [Co(II)(C_6H_5CH=CHCOOH)_2(4,4′- bipy)(H_2O)_5]n has been synthesized with cinnamylic acid, 4,4′-bipy and cobaltous chloride as raw materials. Crystal data for this complex: monoclinic, space group P21/c, a = 1.1481(3), b = 1.1230(2), c = 1.1759(3) nm, β = 97.054(4)o, V = 1.5046(6) nm~3, Mr= 617.50, Dc = 1.363 g/cm~3, Z = 2, μ(MoKα) = 0.627 mm~(-1), F(000) = 646, S = 1.062, R 0.0443 and wR = 0.1178. The crystal structure shows that two neighboring cobalt(II) ions are linked together by one 4,4′...

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