期刊论文

Li Wei

英文

Chinese Journal of Structural Chemistry

0254-5861

2007

26

2

206-210

Project supported by the Foundation of Education Committee of Hunan Province （05C001）, Foundation of Hengyang Sci ＆ Tech Bureau （2005Cg10-23） and Fund for Distinguished Young Scholars of Hangyang Normal University （No. 2006）

本校为其他机构

The title complex (C_(26)H_(24)CuN_2O_5, Mr = 508.01) has been synthesized by o-methylbenzoic acid, 2,2'-bipyridine (bipy) and copper perchlorate in the mixed solvent of water and methanol. It crystallizes in orthorhombic, space group P2_12_12_1 with a = 0.70814(10), b = 1.6953(3),c = 1.9539(3) nm, V= 2.3457(6) nm~3, Dc= 1.439 g/cm~3, Z= 4,μ = 0.971 mm~(-1), F(000) = 1052, R= 0.0432 and wR = 0.0860. The structural determination shows that the copper atom is coordinated by three oxygen atoms from two o-methylbenzoic acids and one water molecule...