期刊论文

Li Wei

英文

Chinese Journal of Structural Chemistry

0254-5861

2007

26

11

1267-1270

Supported by the Foundation of Education Committee of Hunan Province （06C195）, the Research Award Fund for 0utstanding Young Teachers of Hengyang Normal Univcrsity （2006）, and the construct program of the Key Discipline in Hunan Province

本校为第一且通讯机构

One new cadmium complex [Cd(phen)3]·(ClO 4)2·(p-MBA)2·(H 2O)2 has been hydrothermally synthesized by reacting p-methylbenzoic acid (p-MBA), 1,10-phenanthroline (phen) and cadmium perchlorate. It crystallizes in the triclinic system, space group P1̄, with a = 1.2809(3), b = 1.3431(3), c = 1.3734(3) nm, α = 84.259(4), β = 71.603(3), γ = 74.424(3)°, V = 2.1594(8) nm3, Dc = 1.532 g/cm3, Z = 2, F(000) = 1008, μ = 0.697 mm-1, R = 0.0646 and wR = 0.1648. The crystal structure shows that the cadmium ion is coordinated with six nitrogen atoms f...