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Synthesis, Crystal Structure and Electrochemical Properties of a One-dimensional Chain Coordination Polymer [Cu(phen)(2,4,6-TMBA)_2(H_2O)]_n

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成果类型:
期刊论文
作者:
Li Wei*;Li Chang-Hong;Yang Ying-Qun;Kuang Yun-Fei
通讯作者:
Li Wei
作者机构:
[Kuang Yun-Fei; Yang Ying-Qun; Li Wei] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
[Li Chang-Hong] Hunan Inst Technol, Dept Chem Engn, Hengyang 421002, Peoples R China.
通讯机构:
[Li Wei] H
Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
语种:
英文
关键词:
Cu(Ⅱ) coordination polymer;crystal structure;electrochemical property analysis
关键词(中文):
铜(Ⅱ)配位聚合体;晶体结构;电化学性质;合成
期刊:
Chinese Journal of Structural Chemistry
ISSN:
0254-5861
年:
2008
卷:
27
期:
2
页码:
210-214
基金类别:
Project supported by the Foundation of Education Committee of Hunan Province(06C195) and the Research Award Fund for Outstanding Young Teachers of Hengyang Normal University(2006) and Supported by the constrUct program of the key discipline in hunan proviace.
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
A one-dimensional chain coordination polymer [Cu(phen)(2,4,6-TMBA)(2)(H2O)](n) has been synthesized by reacting 2,4,6-trimethyl-benzoic acid, 1,10-phenanthroline and Cu(II) perchlorate and its structure was characterized. Crystal data for this complex: tetragonal, space group 14(1), a = 2.0293(3), b = 2.0293(3), c = 1.3758(2) nm, alpha = beta = gamma = 90 degrees, V = 5.6657(13) nm(3), D-c= 1.379 g/cm(3), Z = 8, mu(MoK alpha) = 0.815 mm(-1), M-r = 588.14, F(000) = 2456, S = 1.047, R = 0.0459 and wR = 0.1053. The crystal structure shows that two neighboring Cu(II) ions are linked together by on...

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