期刊论文

Zhang Shao-Hua

英文

Chinese Journal of Structural Chemistry

0254-5861

2008

27

12

1427-1430

Project supported by the Fund of Science and Technology Committee of Human Province （2008FJ3023）, the Research Award Fund for Outstanding Young Teachers of Hengyang Normal University （2006） and Key Subject Fund of Hunan Province

本校为第一且通讯机构

One novel complex [Ni(phen)_3]·(C_8H_(12)O_4)·(H_2O)_(14) with hexane dicarboxylic acid and 1,10-phenanthroline has been hydrothermally synthesized and characterized. Crystal data: monoclinic, space group C2/c, a = 2.3475(5), b = 1.2208(2), c = 1.9499(4) nm, β = 114.682(3)°, V = 5.0778(16) nm~3, D_c = 1.339 g/cm~3, Z = 4, μ(MoKα) = 0.458 mm~(–1), F(000) = 2168, GOOF = 1.014, R = 0.0401 and w_R = 0.0961. The nickel(II) center in the title complex is coordinated with six nitrogen atoms of three 1,10-phenanthroline molecules, giving a disto...