期刊论文

Li Chang-Hong

英文

Chinese Journal of Structural Chemistry

0254-5861

2011

30

10

1493-1496

10.14102/j.cnki.0254-5861.2011.10.020

Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [11JJ9006]; Science and Technology Committee of Hunan Province [2009FJ3101]; Science and Technology Committee of Hengyang [2011kj25]

本校为第一机构

The title complex has been synthesized with 2,2.-biphenyl dicarboxylic acid and 1,10-phenanthroline (phen) in the solvent mixture of water and methanol. It crystallizes (C_(38)H_(28)CuN_4O_6, M _r = 700.1) in triclinic, space group P1 with a = 1.0868(2), b = 1.2175(2), c = 1.6206(3) nm, α = 110.161(2), β = 102.605(3), γ = 93.667(2)°, V = 1941.6(6) nm~3, Dc = 1.198 g/cm ~3, Z = 2, F(000) = 722, R = 0.0558 and wR = 0.1208. The crystal structure shows that the copper atom is coordinated with one oxygen atom from 2,2.-bphenyl dicarboxylic acid ...