期刊论文

Chen Zhi-Min

英文

Chinese Journal of Structural Chemistry

0254-5861

2012

31

12

1803-1809

10.14102/j.cnki.0254-5861.2012.12.016

Supported by the Scientific and Technological Program of Hunan Provincial Department of Science and Technology （No. 2010JT4041）, Hunan Provincial Department of Education （No. 11 CO 186）, Hunan Provincial Key Discipline Construction and Hunan College Key Laboratory of Functional Organometallic Materials

本校为第一且通讯机构

The novel complex [Zn_2(Mba)_3(Phen)_2EtOH)]·ClO_4 (Hmba=methoxybenzoic acid, Phen=1,10-phenanthroline, EtOH=ethanol) was synthesized by hydrothermal reactions, and its structure was determined by X-ray diffraction. The crystal belongs to the triclinic system, space group Pi with a=1.15362(1), b=1.3655(3), c=1.61451(1) nm, α=72.842(2), β=83.259(3), γ=72.083(2)°, V=2.3112(6) nm3, Z=2, μ(MoKα)=11.71 cm~(-1), F(000)=1120, R=0.0552 and wR=0.1157 (I > 2σ(I)). The two centric zinc(Ⅱ) ions in the complex locate in a distorted octahedral coord...