期刊论文

Zhang Shao-Hua

英文

Chinese Journal of Structural Chemistry

0254-5861

2012

31

11

1681-1684

10.14102/j.cnki.0254-5861.2012.11.022

Supported by the Fund of Science and Technology Committee of Hunan Province （No. 2012GK3030）, the Scientific Research Fund of Hunan Provincial Education Department （No. B21018） and the Hengyang Bureau of Science ＆ Technology （No. 2011kG28）

本校为第一且通讯机构

A dinuclear cobalt(Ⅱ) complex [Co_2(α-furacrylato)_4(Phen)_2(H_2O)].C_2H_5OH has been synthesized with a-furacrylic acid and 1,10-phenanthroline as the ligands, and its crystal structure was determined. The crystal is of monoclinic system, space group C2/c with a = 1.07388(8), β = 2.4300(2), c = 1.86708(14) nm, β = 104.3830(10)°, V = 4.719.4(7) nm~3, D_c = 1.503 g/cm~3, Z = 2, F(000) = 2196, GOOF = 1.053, the final R= 0.0343 and wR = 0.0883. The crystal structure shows that two neighboring cobalt(Ⅱ) ions are linked by the bridging coordin...