期刊论文

Li Chang-Hong

英文

Chinese Journal of Structural Chemistry

0254-5861

2012

31

9

1373-1377

10.14102/j.cnki.0254-5861.2012.09.021

Supported by the Fund of Hunan Provincial Natural Science Foundation of China （No. 11J J9006）, and Science and Technology Committee of Hunan Province （2012WK3029, 2012GK3031, 2011 FJ3037）

本校为其他机构

The three-dimensional framework copper（Ⅱ） coordination polymer with basic copper carbonate and 3-（pyridin-2-yl）-1,2,4-triazole has been hydrothermally synthesized. It crystallizes in monoclinic space group P21/c, with a = 1.20860（3）, b = 1.29581（2）, c = 1.67863（3） nm, β = 116.0280（2）°, C21H12Cu3N12, Mr = 623.05, V = 2.36230（9） nm3, Dc = 1.752 g/cm3, Z = 4, F（000） = 1236, GOOF = 1.037, the final R = 0.0408 and wR = 0.1141. Every unit cell contains three copper atoms and three 3-（pyridin-2-yl）-1,2,4-triazole ligands. Every ce...