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Crystal Structure and Thermal Stability Properties of a New 1D Chain Cu(II) Coordination Polymer with2,3-Pyridinedicarboxylic Acid as the Ligand

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成果类型:
期刊论文
作者:
Li Wei*;Li Chang-Hong;Li Heng-Feng;Xu Jin-Sheng;Li Li
通讯作者:
Li Wei
作者机构:
[Xu Jin-Sheng; Li Wei] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
[Li Heng-Feng; Li Wei] Cent S Univ, Sch Mat Sci & Engn, Changsha 410083, Peoples R China.
[Li Chang-Hong] Hunan Inst Technol, Dept Chem Engn, Hengyang 421002, Peoples R China.
[Li Li] Hengyang Yile New Mat Co Ltd, Hengyang 421421, Peoples R China.
通讯机构:
[Li Wei] H
Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
语种:
英文
关键词:
copper(II) coordination polymer;crystal structure;thermal stability properties
关键词(中文):
铜配位聚合物;吡啶二羧酸;晶体结构;一维链状;热稳定性能;铜(Ⅱ);配体;水分子
期刊:
Chinese Journal of Structural Chemistry
ISSN:
0254-5861
年:
2013
卷:
32
期:
10
页码:
1567-1571
基金类别:
Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [11JJ9006]; Key Project of Science and Technology Plan of Hunan Province [2012FJ2002]; Science and Technology Plan of Hunan Province [2012GK3031, 2012WK3029]; Construct Program of the Key Discipline in Hunan Province
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
A new 1D chain copper coordination polymer [Cu-2(H2L)(2)(C10H8N2)(H2O)(2)](n)center dot 3n(H2O) with 2,3-pyridinedi carboxylic acid (H2L) and 2,2'-bipyridine (2,2'-bipy) as ligands has been synthesized in the mixed ethanol and water solvents. Crystal data for this complex are as follows: monoclinic, space group P2(1)/c, a = 7.7713(7), b = 27.478(3), c = 13.2621(13) angstrom, beta = 100.6940(10)degrees, V = 2782.8(5) angstrom(3), D-c = 1.722 g/cm(3), Z = 4, mu = 1.61 mm(-1), F(000) = 1472, the final R = 0.0363 and wR = 0.0933. In the crystal structure, the whole molecule consists of two cooper ...

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