期刊论文

Yang Ying-Qun

英文

Chinese Journal of Structural Chemistry

0254-5861

2013

32

11

1663-1666

10.14102/j.cnki.0254-5861.2013.11.009

Supported by the Fund of Science mid Technology CommiRee of Hunan Province （No. 2012GK3030）, the Scientific Research Fund of Hunan Provincial Education Department （No. l 1C0186）, the Hengyang Bureau of Science and Technology （No. 2011 kG28） and the Key Discipline Project of Hunan Province

本校为第一且通讯机构

A new Cd(II) complex [Cd(C12H6O4N 2)(Phen)2(H2O)]·3H2O with 2,2′-bipyridine-3,3′-dicarboxylic acid as a ligand has been synthesized. Crystal data for the title complex are as follows: monoclinic, space group P21/n, a = 12.8458(5), b = 17.9131(7), c = 15.2960(6) Å, β = 111.7430(10)°, V = 3269.3(2) Å3, D c = 1.581 g/cm3, Z = 4, μ(MoKα) = 0.731 mm -1, F(000) = 1580, the R = 0.0244 and wR = 0.0605. In the title complex, the central Cd(II) ion is located in a distorted octahedral coordination environment. The electrochemical and fluorescent...