期刊论文

Yang Ying-Qun

英文

Chinese Journal of Structural Chemistry

0254-5861

2013

32

12

1841-1844

10.14102/j.cnki.0254-5861.2013.12.009

This project was supported by the Fund of Science and Technology Committee of Hunan Province （No. 2012GK3030）, the Scientific Research Fund of Hunan Provincial Education Department （No. 11C0186） and the Key Project of Science and Technology Plan of Hunan Province （2012FJ2002）

本校为第一且通讯机构

A new copper(II) complex Cu2(L)4(2,2′-bipy) 2(H2O)2 (1) has been synthesized with 2-benzoylbenzoic acid (HL) and 2,2′-bipyridin as ligands. The crystal belongs to a monoclinic system with space group Cc, a = 13.9979(11), b = 15.9888(13), c = 30.306(3) Å, β = 100.8700(10)°, V = 6661.1(10) Å3, Dc = 1.372 g/cm3, Z = 8, F(000) = 2840, the final GOOF = 1.018, R = 0.0685, and wR = 0.1731. There are two mononuclear Cu(L)2(2,2′-bipy)(H2O) units in the crystal of 1. Each Cu(II) cation is coordinated by five atoms. The magnetic and fluorescent pro...