期刊论文

Li Chang-Hong

英文

Chinese Journal of Structural Chemistry

0254-5861

2014

33

6

947-951

10.14102/j.cnki.0254-5861.2014.06.022

Supported by the Natural Science Foundation of Hunan Province（No.11JJ9006） Key Project of Science and Technology Plan of Hunan Province（2012FJ2002） the Construct Program of the Key Discipline in Hunan Province

本校为其他机构

A new complex has been synthesized with o-methylbenzoyl-benzoic acid (HL) and 1,10-phenanthroline (phen) in the mixture of water and ethanol. It crystallizes in monoclinic, space group C2/c with a = 13.6328(18), b = 17.7876(18), c = 19.998(2) A, β = 104.720(4)°，C_(54)H_(48)N_4O_(11)Zn, Mr = 994.33, V= 4690.2(9) A~3, D_c = 1.408 g/cm~3, Z = 4, F(000) = 2072, μ(MoKa) = 0.59 mm~(-1), R = 0.0736 and wR = 0.2029. The crystal structure shows that the zinc ions are coordinated with two oxygen atoms from two HL molecules and four nitrogen atoms fro...