期刊论文

Zhang Zhi-Jian

英文

Chinese Journal of Structural Chemistry

0254-5861

2014

33

9

1319-1325

10.14102/j.cnki.0254-5861.2014.09.031

Natural Science Foundation of Hunan ProvinceNatural Science Foundation of Hunan Province [13JJ3112]; Scientific & Technological Projects of Hunan Province [2013TZ2025, 2014FJ3060]; Scientific Research Fund of Hunan Provincial Education Department of ChinaHunan Provincial Education Department [14C0171]; Foundation of Key Laboratory of Functional Organometallic Materials, University of Hunan Province [13K03, 13K04, 13K05]; Science Foundation of Hengyang Normal University [12C45, 13A21]

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The Schiff base organotin(IV) complex {[4-Et_2NC_6H_3(O)C=NC_6H_3(O)-5-NO_2](n-Bu_2Sn)}_2 has been synthesized via the reaction between 4-(diethylamino) salicylaldehyde-2-amino-4-nitrophenol Schiff base (H_2L) and dibutyltin oxide. Complex C1 has been characterized by IR, ~1H NMR, ~(13)C NMR spectra, and elemental analysis, and its crystal structure was determined by X-ray diffraction. It crystallizes in the monoclinic system, space group P2_(1/n) with a = 15.6559(8), b = 9.1657(5), c = 18.8351(10) A, β = 107.3440(10)°, Z = 4, V = 2579.9(2) A...