期刊论文

Li Wei

英文

Chinese Journal of Structural Chemistry

0254-5861

2015

34

6

973-978

10.14102/j.cnki.0254-5861.2011-0776

Supported by the Key Project of Science and Technology Plan of Hunan Province （2012FJ2002）, Science and Technology Committee of Hengyang （2013KG77）, and the Construct Program of the Key Discipline in Hunan Province

本校为其他机构

A new dinuclear manganese complex [Mn_2(L)_2(2,2?-bipy)_2(H_2O)_5]_2·3H_2O has been synthesized with MnSO_4·H_2O, 2,2?-bibenzoic acid (H_2L) and 2,2?-bipyridine(2,2?-bipy) in the mixed solvent ethanol and water. It crystallizes in monoclinic, space group P1 with a = 9.9944(10), b = 21.939(2), c = 25.628(3) A, α = 108.429(3), β = 100.613(4), γ = 102.821(3)o, V = 4997.9(9) A~3, D_c = 1.355 g/cm~3, Z = 2, F(000) = 2108, GOOF = 1.074, the R = 0.0626 and wR = 0.1531. The structure of the complex contains two [Mn_2(L)_2(2,2?-bipy)2] units, ten c...