期刊论文

Jiang Wu-Jiu

英文

Chinese Journal of Structural Chemistry

0254-5861

2017

36

6

925-936

10.14102/j.cnki.0254-5861.2011-1435

Supported by Natural Science Foundation of Hunan Province（No.2016JJ4008） the Innovation Platform Open Fund Project of Hunan Provincial Education Department of China（No.16K011） the Open Fund Project of Key Laboratory of Functional Organometallic Materials of Hengyang Normal University（Nos.GN16k01,GN16K03） the Scientific and Technological Projects of Hengyang（No.2016KJ04）

本校为第一且通讯机构

2-Oxo-butyric acid salicylacylhydrazone dibenzyltin (IV) complexes 1 {[o-OHC_6H_4(O)C=N-N=C(Et)COO](CH_3OH)[(C_6H_5CH_2)_2Sn]}_2 and 2 {[o-OH-C_6H_4(O)C=N-N=C(Et)-COO](CH_3OH)[(2,4-Cl_2C_6H_3CH_2)_2Sn]}_2 have been synthesized. The complexes were characterized by IR, 1H, 13C and 119Sn NMR spectra, elemental analysis and thermal stability analysis, and the crystal structures were determined by X-ray diffraction. The crystal of complex 1 belongs to triclinic system, space group P1 with a = 8.9121(6), b = 10.3875(7), c = 14.5658(10) A, α = 89.534...