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Synthesis,Electrochemical and Fluorescent Properties of a New Zinc(Ⅱ) Complex through Self-assembly Reaction of 2,2'-Bipyridine-3,3'-dicarboxylic Acid

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成果类型:
期刊论文
作者:
Tan Xiong-Wen;Li Chang-Hong;Li Heng-Feng*;Yang Ying-Qun*
通讯作者:
Li Heng-Feng;Yang Ying-Qun
作者机构:
[Li Chang-Hong; Li Heng-Feng; Tan Xiong-Wen] Cent S Univ, Sch Mat Sci & Engn, Changsha 410083, Hunan, Peoples R China.
[Tan Xiong-Wen; Yang Ying-Qun] Hengyang Normal Univ, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat Hunan Prov, Hengyang 421008, Peoples R China.
[Li Chang-Hong] Hunan Inst Technol, Dept Chem Engn, Hengyang 421002, Peoples R China.
通讯机构:
[Li Heng-Feng] C
[Yang Ying-Qun] H
Cent S Univ, Sch Mat Sci & Engn, Changsha 410083, Hunan, Peoples R China.
Hengyang Normal Univ, Dept Chem & Mat Sci, Key Lab Funct Organometall Mat Hunan Prov, Hengyang 421008, Peoples R China.
语种:
英文
关键词:
zinc(Ⅱ) complex,crystal structure;electrochemical and fluorescent properties
关键词(中文):
电化学性能;锌(Ⅱ);荧光性质;自组装反应;合成;联吡啶;二羧酸
期刊:
Chinese Journal of Structural Chemistry
ISSN:
0254-5861
年:
2017
卷:
36
期:
2
页码:
310-315
基金类别:
Supported by the Open Fund Project of Key Laboratory of Functional Organometallic Materials of Hengyang Normal University (GN15K02) and the Science Foundation of Hengyang Normal University (16D06)
机构署名:
本校为通讯机构
院系归属:
化学与材料科学学院
摘要:
A new Zn(Ⅱ) complex [Zn(Phen)_2(C_(12)H_6O_4N_2)(H_2O)]·3H_2O with 2,2'-bipyridine-3,3'-dicarboxylic acid and 1,10-phenanthroline (Phen) as ligands was synthesized, and the crystal data are as follows: monoclinic, space group P2_1/n, a = 12.5581(11), b = 17.3382(17), c = 15.6687(14) A,β= 110.579(2)°,M_r = 731.02,V = 3193.9(5) A~3, D_c = 1.520 g/cm~3, Z = 4, μ(MoKa) =0.833 mm~(-1), F(000) = 1508, the final R= 0.0431 and wR= 0.0936. In the title complex,the central Zn(Ⅱ) ion is located in a distorted octahedral coordination environment. The...

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