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Synthesis, Structure and Biological Activities of a Novel Anionic Organotin (IV) Complex {[(p- ClC_6H_4CH_2)Sn(H_2O)(Cl)_2OCOCH(O)CH(O) CO_2Sn(H_2O)(Cl)_2(p-ClC_6H_4CH_2)]·2(HNEt_3)}

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成果类型:
期刊论文
作者:
He Tang-Feng;Zhang Fu-Xing*;Yao Shu-Fen;Zhu Xiao-Ming;Sheng Liang-Bing;...
通讯作者:
Zhang Fu-Xing
作者机构:
[Zhang Fu-Xing] Hengyang Normal Univ, Dept Chem & Mat Sci, Coll Hunan Prov, Hengyang 421008, Hunan, Peoples R China.
Hengyang Normal Univ, Key Lab Funct Met Organ Cpds Hunan Prov, Coll Hunan Prov, Hengyang 421008, Hunan, Peoples R China.
Hengyang Normal Univ, Key Lab Funct Organometall Mat, Coll Hunan Prov, Hengyang 421008, Hunan, Peoples R China.
通讯机构:
[Zhang Fu-Xing] H
Hengyang Normal Univ, Dept Chem & Mat Sci, Coll Hunan Prov, Hengyang 421008, Hunan, Peoples R China.
语种:
英文
关键词:
ANIONIC;organotin(IV);COMPLEX;D-tartaric;acid;synthesis;structure;vitro;anticancer;activity
期刊:
Chinese Journal of Structural Chemistry
ISSN:
0254-5861
年:
2018
卷:
37
期:
12
页码:
1899-1906
基金类别:
the Open Fund Project innovation platform of Key Laboratory of Higher Educational Institutions of Hunan Province (GN16K01) Scientific & Technological Projects of Hengyang (2016KL03) Aid programs for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province the Key Discipline of Hunan Province,Project funding for research and innovation experiment of university students in Hunan Province.
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
A novel anionic organotin(IV) complex I {[p-ClC6H4CH2)Sn(H2O)(Cl)(2)OCOCH(O)CH(O)CO2Sn(H2O)(Cl)(2)(p-ClC6H4CH2)]center dot 2(HNEt3)} (1) was synthesized by the reaction of di(p-chlorobenzy)tin dichloride with the D-tartaric acid in 2:1 molar in the presence of an organic base triethylamine. The structure was characterized by elemental analysis, IR, TG, XRD and single-crystal X-ray diffraction. It crystallizes in triclinic, P-(1) over bar space group, with a = 0.7067(1), b = 1.9762(3), c = 2.2383(3) nm, alpha = 91.544(2)degrees, beta = 90.075(2)degrees, gamma = 90.110(2)degrees, V = 3.1247(7) n...

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