期刊论文

Li Yu-Lin;Li Chang-Hong

英文

Chinese Journal of Structural Chemistry

0254-5861

2018

37

5

819-824

10.14102/j.cnki.0254-5861.2011-1897

Supported by the Scientific Research Found of Hunan Provincial Education Department of China（17A049,17C0226） Industry and Research Key Project of Hengyang City（2017KJ155,2017KJ193） Doctoral Scientific Research Foundation of Hengyang Normal University（17D01）

本校为第一且通讯机构

A new binuclear copper(II) complex [Cu_2(Hpt)_2(TNCA)_2(H_2O)_2]·4H_2O (1) has been synthesized with copper acetate, 5-oxo-4-oxa-tricyclo[4.2.1.0]nonane-9-carboxylic acid (TNCA) and 3-(pyridin-2-yl)-1,2,4-triazole (Hpt). It crystallizes in the triclinic space group P1, with a = 8.8199(18), b = 14.278(3), c = 15.269(3) A, α = 76.21(3)º, β = 81.07(3)º, γ = 76.07(3)º, V = 1802.7(6) A~3, D_c = 1.636 g/cm~3, Z = 2, F(000) = 916, the final GOOF = 1.051, R = 0.0556 and wR = 0.1388. The whole molecule consists of two copper ions bridged by two μ...