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Synthesis, Crystal Structure and Properties of a 1D Heteronuclear Cobalt-sodium Polymer with Bridging Ligand 2-(2-Hydroxy-3-methoxybenzylidene) Hydrazinecarbothioamide

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成果类型:
期刊论文
作者:
Li Yu-Lin;Li Wei*;Li Chang-Hong*;Tan Xiong-Wen
通讯作者:
Li Wei;Li Chang-Hong
作者机构:
[Tan Xiong-Wen; Li Yu-Lin; Li Wei] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
[Li Chang-Hong] Hunan Inst Technol, Dept Chem Engn, Hengyang 421002, Peoples R China.
[Li Wei] Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.
通讯机构:
[Li Wei; Li Chang-Hong] H
[Li Wei] K
Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
Hunan Inst Technol, Dept Chem Engn, Hengyang 421002, Peoples R China.
Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.
语种:
英文
关键词:
heteronuclear;cobalt-sodium polymer;electrochemical and fluorescent properties
关键词(中文):
聚合物;水晶结构;合成;性质;钠;钴;三斜晶系
期刊:
Chinese Journal of Structural Chemistry
ISSN:
0254-5861
年:
2018
卷:
37
期:
10
页码:
1651-1655
基金类别:
Supported by Scientific Research Found of Hunan Provincial Education Department of China (17A049, 17C0226), Industry and Research Key Project of Hengyang City (2017K J155, 2017K J193) and Doctoral Scientific Research Foundation of Hengyang Normal University (17D01 )
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
A new cobalt-sodium coordination polymer vertical bar CoNa(C9H9N3O2S)2 center dot H2O vertical bar(2)center dot C2H3N center dot H2O (1) has been synthesized with cobalt chloride, 2-(2-hydroxy-3-methoxybenzylidene)hydrazinecarbothio amide (L) and sodium hydroxide. It crystallizes in the triclinic space group P (1) over bar, with a = 9.972(4), b = 10.923(4), c = 13.489(5) angstrom, alpha = 108.005(10), beta = 92.728(10), gamma = 93.16(1)degrees, V = 1392.0(9) angstrom(3), M-r = 1151.95, D-c = 1.374 g/cm(3), Z = 2, F(000) = 592, the final GOOF = 1.126, R = 0.1091 and wR = 0.2412. Each unit molec...

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