期刊论文

Kuang Dai-Zhi

英文

Chinese Journal of Structural Chemistry

0254-5861

2018

37

8

1265-1271

10.14102/j.cnki.0254-5861.2011-1923

Supported by the Innovation Platform Open Foundation for Colleges and Universities of Hunan Province（No.16k011） Key Laboratory of Functional Organometallic Materials of Hengyang Normal University（No.GN16K01） Scientific＆Technological Projects of Hengyang（No.2016KJ03）

本校为第一且通讯机构

A two-dimensional supramolecular compound di-n-butyltin piperonylate, {(μ3-O)(μ2-OMe)(n-Bu2Sn)2[O2CAr(C2H4O)]}2 constructed by hydrogen bonds with a Sn4O4 ladder-like framework, was obtained by the microwave-assisted solvothermal reaction of di-n-butyltin oxide precursor with the piperonylic acid in methanol environments. The composite was characterized by elemental analysis and IR (1H,13C and119Sn) NMR spectra. The compound crystallizes in monoclinic system, space group P21/n with a = 13.3690(12), b = 14.1442(14), c = 16.4022(16) Å, β = 10...