The triphenyltin complex with salicylidene-2-aminophenol (C_(31)H_(24)NO_2Sn, 1) has been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, and X-ray single-crystal diffraction. The complex crystallizes in monoclinic system, P2_1/c space group with a = 1.09515(8), b = 1.17739(8), c = 2.29075(14) nm, β = 117.070(4)°, V = 2.6302(3) nm~3, Z = 4, D_c = 1.417 g/cm~3, μ = 0.999 mm~(-1), F(000) = 1123, R = 0.0472 and wR = 0.1169. X-ray single-crystal diffraction showed that 1 demonstrates a one-dimens...