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Synthesis and the Fluorescent,Magnetic and Thermal Stability Properties of a New Terbium (III) Complex Tb(C_(20)H_(14)O_3N)_3(C_(12)H_8N_2)(H_2O)·H_2O

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成果类型:
期刊论文
作者:
Yang Ying-Qun*;Yang Ying;Li Jiao-Di;Li Wei*
通讯作者:
Yang Ying-Qun;Li Wei
作者机构:
[Yang Ying-Qun; Li Wei] Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.
[Yang Ying-Qun; Li Wei] Hunan Prov Coll, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.
[Yang Ying; Li Jiao-Di; Yang Ying-Qun; Li Wei] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
通讯机构:
[Yang, YQ; Li, W] K
[Yang, YQ; Li, W] H
Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.
Hunan Prov Coll, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.
Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
语种:
英文
关键词:
terbium(III) complex;crystal structure;fluorescent and magnetic properties
期刊:
Chinese Journal of Structural Chemistry
ISSN:
0254-5861
年:
2019
卷:
38
期:
12
页码:
2129-2134
基金类别:
This project was supported by the cooperative project of Hengyang Normal University with Hengyang Yile New Materials Co.,Ltd.(HXKJ201905) the Natural Science Foundation of Hunan Province(2019JJ60021,2019JJ50013) the Scientific Research Found of Hunan Provincial Education Department ofChina(17A049) the Industry and Research Key Project of Hengyang City(2018kKJ016,2017KJ155,2017KJ193)。
机构署名:
本校为通讯机构
院系归属:
化学与材料科学学院
摘要:
A new terbium(III) complex Tb(C20H14O3N)(3)(C12H8N2)(H2O)center dot H2O has been synthesized with 2-diphenylanine carbonyl benzoic acid and 1,10-phenanthroline as ligands. Crystal data for the complex are as follows: triclinic, space group P (1) over bar, a =11.6034(6), b = 16.2465(8), c = 16.4427(8) angstrom, alpha = 73.168(5)degrees, beta = 88.655(4)degrees, gamma = 82.865(4)degrees, V= 2943.7(3) angstrom(3), D-c = 1.494 g/cm(3), Z = 2, mu(MoK alpha) = 1.272 mm(-1), F(000) = 1348, the final R= 0.0535 and wR = 0.0809. The Tb(III) ion is coordinated by nine atoms to give a monocapped square an...

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