Synthesis,Crystal Structure,and Fluorescent and Thermal Stability Properties of Two New Cobalt(II)Complexes with 2,2\'-Bipy as Ligand - 成果

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Synthesis,Crystal Structure,and Fluorescent and Thermal Stability Properties of Two New Cobalt(II)Complexes with 2,2'-Bipy as Ligand

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作者信息关键词期刊信息基础信息归属信息摘要

成果类型：

期刊论文

作者：

Li Yu-Lin;Yang Ying-Qun*;Mao Fang-Fang;Chen Zhi-Min*

通讯作者：

Yang Ying-Qun;Chen Zhi-Min

作者机构：

[Yang Ying-Qun; Chen Zhi-Min] Hunan Prov Coll, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.

[Yang Ying-Qun; Chen Zhi-Min] Hunan Prov Coll, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.

[Yang Ying-Qun; Chen Zhi-Min] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.

通讯机构：

[Yang, YQ; Chen, ZM] H

Hunan Prov Coll, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.

Hunan Prov Coll, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.

Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.

语种：

英文

关键词：

cobalt(II) complex;crystal structure;fluorescence;thermal stability

期刊：

Chinese Journal of Structural Chemistry

ISSN：

0254-5861

年：

2019

卷：

期：

页码：

769-776

DOI：

10.14102/j.cnki.0254-5861.2011-2117

基金类别：

Hunan Provincial Natural Science Foundation of ChinaNatural Science Foundation of Hunan Province [2019JJ60021]; Scientific Research Found of Hunan Provincial Education Department of China [17A049, 17C0226]; Industry and Research Key Project of Hengyang City [2018KJ016]

机构署名：

本校为通讯机构

院系归属：

化学与材料科学学院

摘要：

Two new cobalt(II) complexes [Co-2(2,2'-bipy)(2)(dpa)(2)(H2O)(5)]center dot 4H(2)O (1) and Co(2,2'-bipy)(3)(SO (4))center dot 7.5H(2)O (2) have been synthesized with diaphonic acid (H(2)dpa) and 2,2'-bipyridine (2,2'-bipy) as ligands. In 1, two neighboring cobalt(II) ions are linked together by one bridging diaphonic acid group, forming an asymmetric dinuclear structure. 1 crystallizes in triclinic, space group P (1) over bar with alpha = 9.825(6), b = 13.007(8), c = 19.586(1) angstrom, alpha = 80.773(1)degrees, beta = 77.065(1)degrees, gamma = 85.902(1)degrees, M-r = 431.4, V = 2406.5(3) angs...

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Synthesis,Crystal Structure,and Fluorescent and Thermal Stability Properties of Two New Cobalt(II)Complexes with 2,2'-Bipy as Ligand

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