期刊论文

Tan Yu-Xing

英文

Chinese Journal of Structural Chemistry

0254-5861

2020

39

4

673-681

10.14102/j.cnki.0254-5861.2011-2522

supported by the Hengyang Normal University College Students Innovation and Entrepreneurship Training Program(No.cxcy1944) Scientific Research Fund of Hunan Provincial Education Department of China(No.19C0279) Hengyang Normal University Industrial Supported Project(Nos.HXKJ201907,HXKJ201908,HXKJ201911,HXKJ201946,HXKJ201947) Foundation of Key Laboratory of Functional Organometallic Materials,University of Hunan Province(No.GN19K07)。

本校为第一且通讯机构

Two dibenzyltin compounds,{[C_6H_5O(O)C=N-N=C(Ph)COO] (m-Cl-C_6H_4CH_2)_2-Sn(CH_3OH)}_2(1) and {[p-Me-C_6H_4O(O)C=N-N=C(Ph)COO] (m-Cl-C_6H_4CH_2)_2Sn(CH_3OH)}_2 (2),have been synthesized by microwave "one pot" reaction with benzoylhydrazine (or p-methyl benzhydrazine),phenylglyoxylic acid and di-m-chlorobenzyltin dichloride.Compound 2 contains two crystals 2a and 2b.The compounds have been characterized with IR,elemental analysis,~1H,~(13)C and ~(119)Sn NMR spectra,H RMS.Three crystals are all binuclear molecules with a Sn_2O_2 four-membered ring plane,and each Sn atom center is seven-coordina...