A series of dibutyltin complexes, (Bu2Sn)(2)L, [(Bu2Sn)(2) L](3) and H2LSnBu2, were synthesized by microwave-assisted methanolic solvothermal method, where H4L is [2-(OH)-R-ArCH=NNH](2)CX, and X = O, R = 4-NEt2 (T1), 5-Br (T2); X = S, R = H (T3); R = 5-Br (T4). Their structures were characterized by elemental analysis, IR and (H-1, C-13)-NMR spectra. The molecular structure of T2 was confirmed by X-ray diffraction. The crystal of T2 belongs to monoclinic system, space group Ia. Five-coordinated distorted triangular bipyramids and six-coordinated distorted octahedral configurations were formed ...
