期刊论文

英文

Chinese Journal of Structural Chemistry

0254-5861

2021

40

12

1639-1646

10.14102/j.cnki.0254-5861.2011-3214

Supported by the Innovation Platform Open Foundation for Colleges and Universities of Hunan Province （No. 16k011）； the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province；

本校为第一机构

A series of dibutyltin complexes,(Bu_2Sn)_2L, [(Bu_2Sn)_2L]_3 and H_2LSnBu_2, were synthesized by microwave-assisted methanolic solvothermal method, where H_4L is [2-(OH)-R-ArCH=NNH]_2CX, and X = O, R = 4-NEt_2(T1),5-Br(T2);X = S, R = H(T3);R = 5-Br(T4).Their structures were characterized by elemental analysis, IR and(~1H, ~(13)C)-NMR spectra.The molecular structure of T2 was confirmed by X-ray diffraction.The crystal of T2 belongs to monoclinic system, space group Ia.Five-coordinated distorted triangular bipyramids and six-coordinated distorted octahedral configurations were formed by the coo...