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Syntheses, Crystal Structures, Anticancer Activities and DNA-Binding Properties of the Dibutyltin Complexes Based on Benzoin Aroyl Hydrazone

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成果类型:
期刊论文
作者:
Jiang Wu-Jiu;Tan Yu-Jun;Man Jia-Tai;Tan Yu-Xing
通讯作者:
Tan, YX
作者机构:
[Jiang Wu-Jiu; Man Jia-Tai; Tan Yu-Xing] Hengyang Normal Univ, Key Lab Funct Met Organ Cpds Hunan Prov, Key Lab Funct Organometall Mat,Coll Chem & Mat Sc, Univ Hunan Prov,Hunan Prov Engn Res Ctr Monitorin, Hengyang 421008, Hunan, Peoples R China.
[Tan Yu-Jun] Cent South Univ, Xiangya Hosp, Emergency Dept, Changsha 410008, Peoples R China.
通讯机构:
[Tan, YX ] H
Hengyang Normal Univ, Key Lab Funct Met Organ Cpds Hunan Prov, Key Lab Funct Organometall Mat,Coll Chem & Mat Sc, Univ Hunan Prov,Hunan Prov Engn Res Ctr Monitorin, Hengyang 421008, Hunan, Peoples R China.
语种:
英文
关键词:
dibutyltin;complex;synthesis;crystal structure;DNA
期刊:
Chinese Journal of Structural Chemistry
ISSN:
0254-5861
年:
2022
卷:
41
期:
2
页码:
105-113
基金类别:
Supported by the Scientific Research Fund of Hunan Provincial Education Department of China (No. 19C0279); Functional Metal-organic Compounds of Hunan Science and Technology Innovation Team;
机构署名:
本校为第一且通讯机构
院系归属:
化学与材料科学学院
摘要:
Dibutyltin benzoin benzoyl hydrazone complex I [C6H5(O)C=N-N=C(Ph)CH(Ph)O](2)[(n-Bu)(2)Sn](2) and dibutyltin benzoin salicyl hydrazone complex II [2-(OH)-C6H4(O)C=N-N=C(Ph)CH(Ph)O](2)[(n-Bu)(2)Sn](2) were synthesized and characterized by IR, H-1, C-13 and Sn-119 NMR spectra, FIRMS, elemental analysis and thermal stability analysis, and the crystal structures were determined by X-ray diffraction. The crystal of complex I belongs to monoclinic system, space group P2(1)/n with a = 11.1942(8), b = 10.4754(7), c = 23.6700(17) angstrom, beta = 101.529(2)degrees, Z = 2, V = 2719.6(3) angstrom(3), D-c...

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