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Synthesis and Fluorescent and Magnetic Properties of a New Europium Complex Eu(C_(20)H_(14)O_3N)_3(2,2'-bipy)(H_2O)·H_2O

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成果类型:
期刊论文
作者:
Yang Ying-Qun;Kuang Yun-Fei;Zhu Xiao-Ming
作者机构:
[Kuang Yun-Fei; Yang Ying-Qun; Zhu Xiao-Ming] Hunan Prov Coll, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China.
[Kuang Yun-Fei; Yang Ying-Qun; Zhu Xiao-Ming] Hunan Prov Coll, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.
[Kuang Yun-Fei; Yang Ying-Qun; Zhu Xiao-Ming] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China.
语种:
英文
关键词:
europium(III) complex;crystal structure;fluorescent and magnetic properties
期刊:
Chinese Journal of Structural Chemistry
ISSN:
0254-5861
年:
2021
卷:
40
期:
4
页码:
507-511
基金类别:
supported by the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province (MO20K05); the Foundation of Key Laboratory of Functional Organometallic Materials;University of Hunan Province;
机构署名:
本校为其他机构
院系归属:
化学与材料科学学院
摘要:
A new europium(III) complex Eu(C20H14O3N)(3) (2,2'-bipy)(H2O)center dot H2O has been synthesized with 2-diphenylanine carbonyl benzoic acid and 2,2'-bipyridine as ligands. Crystal data for the complex are as follows: triclinic, space group P (1) over bar, a = 11.3334(5), b = 16.0883(7), c = 17.0116(8) angstrom, alpha = 70.411(4)degrees, beta= 82.435(4)degrees, gamma = 85.095(4)degrees, V = 2894.0(2) angstrom(3) , D-c = 1.484 g/cm(3) , Z = 2, mu = 1.15 mm(-1) , F(000) = 1320 and the final R= 0.0447 and wR = 0.0578. The Eu(III) ion is coordinated by nine atoms to give a monocapped square antipri...

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