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Facile approach to prepare FeP2/P/C nanofiber heterostructure via electrospinning as highly performance self-supporting anode for Li/Na ion batteries

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成果类型:
期刊论文
作者:
Zhan, Li;Song, Xinghao;Deng, Wei;Wei, Tongye;Huang, Li;...
通讯作者:
Wei, TY
作者机构:
[Wang, Chengxin; Zhan, Li; Song, Xinghao; Wei, Tongye; Deng, Wei] Xiangtan Univ, Hunan Inst Adv Sensing & Informat Technol, Xiang Tan 411105, Hunan, Peoples R China.
[Wei, Xiaolin] Xiangtan Univ, Sch Phys & Optoelect, Xiang Tan 411105, Hunan, Peoples R China.
[Wei, Xiaolin] Heng Yang Normal Univ, Sch Phys & Elect Engn, Heng Yang 421008, Hunan, Peoples R China.
[Huang, Li] Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen Key Lab Solid State Batteries, Shenzhen 518055, Guangdong, Peoples R China.
[Huang, Li] Southern Univ Sci & Technol, Guangdong Prov Key Lab Energy Mat Elect Power, Shenzhen 518055, Guangdong, Peoples R China.
通讯机构:
[Wei, TY ] X
Xiangtan Univ, Hunan Inst Adv Sensing & Informat Technol, Xiang Tan 411105, Hunan, Peoples R China.
语种:
英文
关键词:

Li/Na ion battery

;

FeP2

;Electrospinning;Self-supported anode;Initial coulombic efficiency
期刊:
Electrochimica Acta
ISSN:
0013-4686
年:
2022
卷:
403
页码:
139682
基金类别:
National Natural Science Foun-dation of ChinaNational Natural Science Foundation of China (NSFC) [11774298]; Guangdong Provincial Key Laboratory of Energy Materials for Electric Power [2018B030322001]
机构署名:
本校为其他机构
院系归属:
物理与电子工程学院
摘要:
FeP2 and P are promising anode material for lithium and sodium ion storage, due to the high theoretical capacity. However, poor electric conductivity and severe volume expansion limit its actual performance. Herein, we prepared a flexible self-supporting anode material which is consist of FeP2, P and C heterostructure nanofibers with diameter of 150.0-200.0 nm named FeP2 & nbsp;@CNs-700. Here, well-dispersed FeP2 & nbsp;nanoparticles and amorphous phosphorus are confined in carbon nanofiber skeleton, which enhance the material's electron/ion transport and structure stability. As a result, The ...

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