Iodine-Catalyzed Three-Component Cascade Reaction for the Synthesis of Substituted 2‑Phenylnaphtho[1,3]selenazoles under Transition-Metal-Free Conditions

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成果类型：

期刊论文

作者：

Chen, Wenqi;Zhu, Xiaoming;Wang, Fei;Yang, Yuan;Deng, Guobo*;...

通讯作者：

Deng, Guobo;Liang, Yun

作者机构：

[Wang, Fei; Yang, Yuan; Deng, Guobo; Liang, Yun; Chen, Wenqi] Hunan Normal Univ, Natl & Local Joint Engn Lab New Petrochem Mat & F, Key Lab Assembly & Applicat Organ Funct Mol Hunan, Minist Educ,Key Lab Chem Biol & Tradit Chinese Me, Changsha 410081, Hunan, Peoples R China.

[Zhu, Xiaoming] Hengyang Normal Univ, Coll Chem & Mat Sci, Hunan Prov Univ Key Lab Funct Organometall Mat, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Hunan, Peoples R China.

通讯机构：

[Deng, GB; Liang, Y] H

Hunan Normal Univ, Natl & Local Joint Engn Lab New Petrochem Mat & F, Key Lab Assembly & Applicat Organ Funct Mol Hunan, Minist Educ,Key Lab Chem Biol & Tradit Chinese Me, Changsha 410081, Hunan, Peoples R China.

语种：

英文

关键词：

Catalysis;Iodine;Cascade reactions;Metal-free conditions;Molecular iodine;Radical process;Selenium powder;Simple operation;Three component;Transition metals;2 phenylnaphtho[1,3]selenazole;2 phenylnaphtho[2,1 d]selenazole;aldehyde;benzaldehyde derivative;free radical;iodine;naphthalen 2 amine;selenium;unclassified drug;Article;catalysis;chemical reaction;controlled study;electron;oxidation;polymerization;reaction analysis;substitution reaction;synthesis

期刊：

JOURNAL OF ORGANIC CHEMISTRY

ISSN：

0022-3263

年：

2020

卷：

期：

页码：

3349-3357

DOI：

10.1021/acs.joc.9b03154

基金类别：

G.D., Y.L., and Y.Y. received funding from the National Natural Science Foundation of China (21602057, 21572051, 21901071, and 21971061), the Opening Fund of Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education of China), and Hunan Normal University (KLCBTCMR201707 and KLCBTCMR201708). Y.L. received funding from the Science and Technology Planning Project of Hunan Province (2018TP1017), and G.D. received funding from the Hong Kong Scholars program (XJ2017009).

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本校为其他机构

院系归属：

化学与材料科学学院

摘要：

An efficient molecular iodine-catalyzed three-component cascade reaction for the construction of 2-phenylnaphtho[2,1-d]selenazoles from naphthalen-2-amine, aldehydes, and selenium powder has been developed. The present approach has the advantages of metal-free conditions, simple operation, and available raw materials. Moreover, the mechanism of the study pro...

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Iodine-Catalyzed Three-Component Cascade Reaction for the Synthesis of Substituted 2‑Phenylnaphtho[1,3]selenazoles under Transition-Metal-Free Conditions

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