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Facile synthesis of Ag@Cu2O heterogeneous nanocrystals decorated N-doped reduced graphene oxide with enhanced electrocatalytic activity for ultrasensitive detection of H2O2

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成果类型:
期刊论文
作者:
Li, Junhua;Jiang, Jianbo;Xu, Zhifeng;Liu, Mengqin;Tang, Siping;...
通讯作者:
Qian, Dong
作者机构:
[Tang, Siping; Liu, Mengqin; Xu, Zhifeng; Li, Junhua] Hengyang Normal Univ, Coll Chem & Mat Sci, Hengyang 421008, Peoples R China.
[Li, Junhua; Jiang, Jianbo; Qian, Dong] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China.
[Li, Junhua] Hengyang Normal Univ, Key Lab Funct Met Organ Cpds Hunan Prov, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China.
[Jiang, Jianbo] Jishou Univ, Coll Chem & Chem Engn, Jishou 416000, Peoples R China.
[Yang, Chunming] Hunan Normal Univ, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China.
通讯机构:
[Qian, Dong] C
Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China.
语种:
英文
关键词:
Hydrogen peroxide;Nonenzymatic sensor;Ultrasensitive detection;Ag@Cu2O nanocrystals;N-doped reduced graphene oxide
期刊:
Sensors and Actuators B-Chemical
ISSN:
0925-4005
年:
2018
卷:
260
页码:
529-540
基金类别:
National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21505035, 21171174, 21472038]; Provincial Natural Science Foundation of HunanNatural Science Foundation of Hunan Province [2016JJ3028, 09JJ3024]; Scientific Research Projects of Education Department of Hunan Province [16A029, 15A027]; Hengyang Normal University [16D04]; Aid Programs for Innovative Team and Key Discipline in Education Department of Hunan Province
机构署名:
本校为第一机构
院系归属:
化学与材料科学学院
摘要:
A nanohybrid composed of Ag@Cu2O heterogeneous nanocrystals supported on N-doped reduced graphene oxide (Ag@Cu2O/N-RGO) has been synthesized by a simple wet-chemical method. The resultant composite consists of N-RGO sheets fully and homogeneously coated with a dense layer of Ag@Cu2O nanocrystals. Both Ag and N-RGO are in direct contact with Cu2O, and Ag nanoparticles with sizes of 2-5 nm are mainly deposited on the surface of Cu2O cubes (edge length of 500 nm). The electrochemical studies reveal that the ternary Ag@Cu2O/N-RGO composite exhibit significantly enhanced electrocatalytic activity f...

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