In this paper, We applying infinitesimal form of the transformation groups theory, the ex-istance of Similarity Solutions for steady laminar natural convection flow caused by cheimical diffusion and reaction along a vertical flat plate is presented and proved, While conventration difference between the wall & surroundmg varies in accordance with x1/(3-2a). Furthermore, using Runge-Kutta method we solved similarity equations to obtain varying regularity of physical quantites with parameters at Sc = 0...