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An efficient electrochemical sensor based on multi-walled carbon nanotubes functionalized with polyethylenimine for simultaneous determination of o-nitrophenol and p-nitrophenol

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成果类型:
期刊论文
作者:
Deng, Peihong;Zeng, Ying;Wei, Yanping;Li, Junhua;Yao, Liangyuan;...
通讯作者:
Liangyuan Yao<&wdkj&>Quanguo He
作者机构:
[Deng, Peihong; Zeng, Ying; Li, Junhua] Hengyang Normal Univ, Univ Hunan Prov, Dept Chem & Mat Sci, Key Lab Organometall New Mat, Hengyang 421008, Peoples R China.
[He, Quanguo; Wei, Yanping] Hunan Univ Technol, Sch Life Sci & Chem, Zhuzhou 412007, Peoples R China.
[He, Quanguo; Yao, Liangyuan] Hunan Qianjin Xiangjiang Pharmaceut Joint Stock Co, Zhuzhou 412001, Peoples R China.
[He, Quanguo; Li, Kanghua; Liu, Xia; Ding, Jianhua] Zhuzhou Peoples Hosp, Geriatr Rehabil Dept, Zhuzhou 421007, Peoples R China.
通讯机构:
[Liangyuan Yao] H
[Quanguo He] S
Hunan Qianjin Xiangjiang Pharmaceutical Joint Stock Co., Ltd., Zhuzhou 412001, China<&wdkj&>School of Life Science and Chemistry, Hunan University of Technology, Zhuzhou 412007, China<&wdkj&>Hunan Qianjin Xiangjiang Pharmaceutical Joint Stock Co., Ltd., Zhuzhou 412001, China<&wdkj&>Geriatric Rehabilitation Department, Zhuzhou People’s Hospital, Zhuzhou 421007, China
语种:
英文
关键词:
O-nitrophenol;p-nitrophenol;Simultaneous determination;Carbon nanotubes;Polyethylenimine
期刊:
Microchemical Journal
ISSN:
0026-265X
年:
2023
卷:
186
页码:
108340
基金类别:
Scientific Research Fund of Hunan Provincial Education Department [22C0401]; Project of Key Laboratory of Functional Metal-Organic Compounds of Hunan Province [2022HSKFJJ026]; 2022 Social Development and Transformation of Scientific and Technological Achievements [51318]; Zhuzhou Municipal Science and Technology Bureau [30, 44]; NSFC [61703152]; Hunan Provincial Health Commission Foundation [202216005061]; Hunan Provincial Natural Science Foundation [2018JJ34]; Project of Science and Technology Department of Hunan Province [18A273, 2021JJ50035, 2020JJ4149]
机构署名:
本校为第一机构
院系归属:
化学与材料科学学院
摘要:
In this paper, carboxylated multi-walled carbon nanotubes (MWCNTs-COOH) functionalized with polyethylenimine (PEI) was prepared and a glassy carbon electrode (GCE) modified with the above nanocomposites (denoted as PEI-MWCNTs-COOH/GCE) was fabricated. Using p-nitrophenol (p-NP) and o-nitrophenol (o-NP) as model compounds, the electrocatalysis of the modified electrode was studied. The results show that the sensitivity and selectivity of the modified electrode are significantly improved due to the synergistic effect of MWCNTs-COOH and PEI. The oxidation peak potentials of o-NP and p-NP were sep...

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